Mechanism of Ylide Transfer to Carbonyl Compounds: Density Functional Calculations
نویسندگان
چکیده
منابع مشابه
Sulfur(IV)-mediated transformations: from ylide transfer to metal-free arylation of carbonyl compounds.
The development of a direct ylide transfer to carbonyl derivatives and of a sulfoxide-mediated arylation is presented from a unified perspective. Mechanistic studies (including density functional calculations) support a common reaction pathway and showcase how subtle changes in reactant properties can lead to disparate and seemingly unrelated reaction outcomes.
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2015
ISSN: 1434-193X
DOI: 10.1002/ejoc.201501073